China Plastics ›› 2009, Vol. 23 ›› Issue (05): 42-47.DOI: 10.19491/j.issn.1001-9278.2009.05.008

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Effect of Grafting Agent: ALMA on Preparation of PBA/P(MMA-ITA) Core-Shell Particles and its Application to Toughness of Nylon 6

  

  • Received:2009-01-04 Revised:2009-02-04 Online:2009-05-26 Published:2009-05-26

Abstract: Abstract: Study the effect of grafting agent: allylmethacrylate(ALMA) on preparation of poly(butyl acrylate )/poly(methyl methacrylate - itaconicacid )(PBA/P(MMA-ITA)) core-shell particles and its application to toughness of nylon 6. The paper discusses effect of the amount of ALMA on average diameter of core-shell particle、gel content、mechanical properties and processing properties of toughened nylon 6. Experimental data indicated : grafting agent increase gel content, but no effect on average diameter. Introduce of suitable amount of ALMA enable impact strength and tensile strength of toughened nylon 6 reaching 20kJ/m2 and 35MPa respectively; melt viscosity、crystallinity degree and melting point all is decreased. Observe the section morphology of toughened nylon 6 by scanning electron microscope(SEM), showed that the toughening mechanism conformed to cavitation theory.

Key words: core-shell particle, toughening, nylon 6, grafting agent