Research progress in development and applications of black phosphorene for flame retardancy of polymers

doi:10.19491/j.issn.1001-9278.2022.05.022

Abstract

Abstract:

Black phosphorene is a new type of two?dimensional nanomaterial with unique properties， and its narrow?band semiconductor properties make it a broad application prospect in field?effect transistors， optoelectronic devices， spintroni?cs， gas sensors， and solar cells. In recent years， the use of black phosphorene for the flame retardancy of polymers has become a hot research field. This paper reviewed the latest research progress in the preparation technology and flame retardant mechanism of black phosphorene. The research advances in the use of black phosphorene as a flame retardant for polymers such as epoxy resin， polyurethane and polyacrylonitrile were introduced. Then， the problems in the flame?retardant application of black phosphorus were analyzed， and the future development direction of the black phosphorene?based flame retardants was prospected.

Key words: black phosphorene, 2?dimension nanomaterial, flame retardancy, polymer, research progress

CLC Number:

TQ314.24⁺8

SUN Qi, GAO Xing, CUI Xuemei, LIAN Huiqin, CUI Xiuguo, WANG Xiaodong. Research progress in development and applications of black phosphorene for flame retardancy of polymers[J]. China Plastics, 2022, 36(5): 133-139.

Figures/Tables 7

Fig.1. Atomic architecture of black phosphorus

Fig.2. Flame?retardant mechanisms of black phosphorus for polymers

Fig.3. Comparison of flame retardant mechanism between black phosphorus and red phosphorus

Fig.4. Preparation process of EP/ black phosphorus@MF nanocomposites［30］

Fig.5. Flame retardant performance of EP/black phosphorus nano sheet composites［32］

BP含量/%	弯曲强度/MPa	弯曲模量/MPa
0	62.361 6	2 490.99
0.10	99.490 2	3 381.32
0.20	132.076 0	6 093.95
0.59	110.140 0	4 343.24
0.94	83.573 6	3 280.26

Tab.1. Mechanical properties of EP/black phosphorus nano sheet composites［32］

Fig.6. Preparation process of EP/RuL3@ black phosphorus nano sheet composites［33］

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