›› 2023, Vol. 37 ›› Issue (5): 48-54.

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Preparation and properties of toughened PVC electrical bushing composites

  

  • Received:2023-01-17 Revised:2023-02-20 Online:2023-05-26 Published:2023-05-26

Abstract: Acrylate rubber (ACM), rigid body nano-calcium carbonate (nano-CaCO3), elastomeric butyl acrylate/methyl methacrylate/butadiene ternary copolymer (AMB) were used as tougheners to blend with poly(vinyl chloride) (PVC). The impact properties, tensile properties, processing rheology, and dynamic thermomechanical properties of the as-prepared compounds were investigated. The results indicated that when the mass ratio of PVC/ACM/nano-CaCO3/AMB was set to be 100/10/3/9, the compounds obtain low-temperature impact strength of 27.64 kJ/m2, which was 5 times higher than that of pure PVC. Their low temperature impact strength was 14.91 kJ/m2, which was 4.1 times higher than that of pure PVC. The addition of AMB reduced the glass transition temperature (Tg) of the compounding system, resulting in a decrease in Tg from 93.71 to 86.36 oC.

Key words: poly(vinyl chloride), toughening modification, acrylate rubber, nano-calcium carbonate, butyl acrylate/methyl methacrylate/butadiene terpolyme