中国塑料 ›› 2009, Vol. 23 ›› Issue (04): 20-23 .DOI: 10.19491/j.issn.1001-9278.2009.04.005

• 材料与性能 • 上一篇    下一篇

基体的组成对透明ABS树脂性能的影响

于越 吕洁 李刚 刘明辉 张明耀   

  1. 长春工业大学化学工程学院 长春工业大学
  • 收稿日期:2009-01-04 修回日期:2009-01-17 出版日期:2009-04-26 发布日期:2009-04-26

The effect of composition of matrix on transparent ABS resin properties

  

  • Received:2009-01-04 Revised:2009-01-17 Online:2009-04-26 Published:2009-04-26

摘要: 摘要:采用种子乳液聚合技术合成MBS接枝粉料,采用悬浮聚合技术合成MSAN树脂。分别选用PMMA/SAN-T混合树脂和MSAN树脂作为透明ABS树脂的两种基体,采用熔融掺混技术制备透明ABS树脂。研究PMMA/SAN-T基体的组成对透明ABS树脂性能的影响以及共聚而成MSAN基体对透明ABS树脂性能的影响。结果表明,当基体为PMMA/SAN-T树 脂时,透明ABS树脂的冲击性能随着基体中PMMA含量的增加先增大后减小;透光率先增大后减小,而雾度先减小后增大。以MSAN树脂为基体的透明ABS树脂的力学性能较好,光学性能较差。

关键词: 乳液聚合, 基体, 透明ABS树脂, 冲击强度, 透光率

Abstract: Abstract: a series of poly Methylmethacrylate-Butadiene-Styrene (MBS) resin were synthesized by seeded emulsion polymerization techniques, methylmethacrylate-styrene -acrylonitrile (MSAN) resin was synthesized by suspension polymerization. Matrix polymer of transparent Acrylonitrile-Butadiene-Styrene (ABS) resin were blend of polymethylmethacrylate (PMMA) resin and poly Acrylonitrile-styrene(SAN) resin or methylmethacrylate-styrene-acry- lonitrile(MSAN) resin.TransparentAcrylonitrile-Butadiene-Styrene (ABS) resin was prepared by blending these MBS resins with matrix polymer. Influence of different composions of PMMA/SAN-T on properties of transparent ABS resin were research and the effect of MSAN matrix on property of transparent ABS resin was also studied. It is found that when matrix polymer was PMMA/SAN resin, impact strength and transmittance of transparent Acrylonitrile-Butadiene- Styrene (ABS) resin increase first, and then decrease;Haze of ABS decrease first, and then increase with the increase of content of PMMA in matrix polymer.Transparent ABS resin,with MSAN as matrix, has better mechanical properties but worse optical properties.

Key words: Emulsion Polymerization, Matrix, Transparent ABS Resin, Impact strength, transmittance