中国塑料 ›› 2010, Vol. 24 ›› Issue (05): 81-84 .DOI: 10.19491/j.issn.1001-9278.2010.05.019

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APP/MCA复合阻燃增强聚丙烯的研究

钱立军 韩鑫磊 叶志殷 叶龙健 许国志   

  1. 北京工商大学材料科学工程系 北京工商大学材料系
  • 收稿日期:2009-10-20 修回日期:1900-01-01 出版日期:2010-05-26 发布日期:2010-05-26

Research on Polypropylene Composites Fire-retarded and Reinforced by APP/MCA

Guozhi Xu   

  • Received:2009-10-20 Revised:1900-01-01 Online:2010-05-26 Published:2010-05-26

摘要: 将三聚氰胺氰尿酸盐(MCA)、聚磷酸铵(APP)与聚丙烯(PP)共混,制备了无卤阻燃PP复合材料,采用极限氧指数仪、热失重分析仪、扫描电子显微镜、电子万能试验机等对材料的阻燃性能、热性能和力学性能等进行了表征,研究了APP/MCA的协效阻燃作用及其对材料力学性能的影响规律。结果表明,在材料中添加25份APP/MCA时,材料的极限氧指数随MCA含量的增加先升高后下降,当MCA含量为30 %(质量分数,下同)时,材料的极限氧指数达到最大值24.2 %;材料的力学性能同样随MCA含量的增加而先升高后下降,当MCA含量为30 %时,其拉伸强度比APP单独阻燃PP时提高了50 %,断裂强度和屈服强度均提高10 %以上。

关键词: 三聚氰胺氰尿酸盐, 聚磷酸铵, 聚丙烯, 增强, 阻燃

Abstract: Halogen-free flame-retarded PP composites were prepared by mixing polypropylene(PP) with melamine cyanurate(MCA) and ammonium polyphosphate(APP). The flame-retarding property, thermo property, and mechanical property were characterized using limited oxygen index, thermo gravimetric analyzer, scanning electron microscope, and electronic tensile testing machine. The synergic flame-retarding effect of APP/MCA and its effect on the mechanical properties of PP were discussed. It was found that when the content of APP/MCA was 25 phr, the limited oxygen index and the mechanical properties of PP composites increased firstly and then decreased with increasing content of MCA. When the content of MCA in APP/MCA was 30 % , the limited oxygen index of the composite reached the highest value of 24.2 %, and its tensile strength increased 50 %, its breaking strength and yield strength also increased more than 10 %, compared with the composite flame-retarded by 25 phr APP.

Key words: melamine cyanuric, ammonium polyphosphate, polypropylene, reinforcement, fire-retarding

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