›› 2023, Vol. 37 ›› Issue (10): 125-130.

• • 上一篇    下一篇

氢氧化镁/氢氧化铝复配阻燃剂对可陶瓷化硅橡胶阻燃抗震性能的影响

王林锋,谢继凯,郭家杏,郝智,郭建兵,龙晓琴,敖钱兰,朱妍,伍明蜜   

  1. 贵州大学材料与冶金学院
  • 收稿日期:2023-06-08 修回日期:2023-07-04 出版日期:2023-10-26 发布日期:2023-10-26
  • 基金资助:
    贵大SRT

Effect of magnesium hydroxide/aluminum hydroxide compounding flame retardant on flame retardant and seismic performance of ceramicizable silicone rubber

  • Received:2023-06-08 Revised:2023-07-04 Online:2023-10-26 Published:2023-10-26

摘要: 以硅橡胶(SR)为基体,添加莫来石纤维(MF)、空心玻璃微珠(GB)、碳酸钙(CaCO3)、2,5-二甲基-2,5-双(叔丁基过氧基)己烷、铁红(Fe2O3),制备了母炼胶。通过添加不同份数比的氢氧化铝[Al(OH)3]和氢氧化镁[Mg(OH)2],经过密炼、开炼、硫化制备了可陶瓷化阻燃有机硅橡胶复合材料。结果表明,所制备的可陶瓷化阻燃硅橡胶复合材料中,GB在高温下能够起到黏结桥梁的作用,MF能很好地起到骨架作用,添加30份Mg(OH)2的硅橡胶复合材料,其拉伸强度可达4.93 MPa,同时具有1 450.73 %的断裂伸长率,而极限氧指数(LOI)值可以达到31.8 %,水平垂直燃烧达到V-0级,硅橡胶复合材料在50 Hz频率、5 g加速度、1 050 ℃的温度下燃烧15 min,试样不被烧穿。

关键词: 硅橡胶, 氢氧化铝, 氢氧化镁, 阻燃, 抗震

Abstract: A type of master rubber was prepared using silicone rubber (SR) as a matrix and mullite fiber (MF), hollow glass microbeads (GB), 2,5-dimethyl-2,5-di(tert-butylperoxy)hexane, CaCO3, and Fe2O3 as additives. Then, ceramic-retardable flame-retardant silicone rubber composites were prepared by adding Al(OH)3 and Mg(OH)2 at different parts ratios through open mixing and vulcanization. The results indicated that GB played a role of bonding bridge at a high temperature and MF acted as a skeleton in the preparation of the ceramic-retardable flame-retardant silicone rubber composites. The rubber composite containing 30 parts of Mg(OH)2 obtained a tensile strength of up to 4.93 MPa, elongation at break of 1 450.73 %, and a limiting oxygen index of 31.8 vol%. The silicone rubber composite with a thickness of 6 mm could burn for 15min at a frequency of 50 Hz, 5 g acceleration, and a temperature of 1 050 °C without burning through.

Key words: silicone rubber, flame retardant, aluminum hydroxide, magnesium hydroxide