China Plastics ›› 2015, Vol. 29 ›› Issue (03): 63-69 .DOI: 10.19491/j.issn.1001-9278.2015.03.011

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UV-protective Properties of Transparent Polystyrene/TiO2 Nanocomposite Films with High Particle Loadings

  

  • Received:2014-10-23 Revised:2015-01-22 Online:2015-03-26 Published:2015-03-26

Abstract: The anatase TiO2 nanoparticles with diameter of smaller than 20 nm were prepared in a nonaqueous sol-gel approach, which was modified with 3-(trimethoxysilyl)propyl methacrylate and dispersed in a PS solution in para-xylene. TiO2 containing solution was spin-coated to a film, in which the TiO2 contents was up to 95 wt %. UV-protective properties were examined by a UV-Vis spectrometer. The experiments indicated that the UV-protective property was enhanced with increasing TiO2 content. The transmittance of visible light became saturated, rather than linearly decreased. When the particle content was 95 wt %, the transmissivity was still higher than 82 %.

Key words: polystyrene, nano-titanium dioxide, high particle content, high transparency, ultraviolet shielding