Research progress in gas barrier polymer/graphene composites

doi:10.19491/j.issn.1001-9278.2021.12.023

Abstract

Abstract:

The permeation theory of small gas molecules and gas barrier model were introduced. The preparation methods of gas barrier graphene/polymer composites and the characterization methods of gas barrier properties were reviewed. The main factors affecting the gas barrier properties of the graphene/polymer composites and the corresponding improvement measures were analyzed and summarized. The future research directions were also prospected.

Key words: permeation theory of small gas molecules, gas barrier model, graphene, composite, preparation method, characterization means

CLC Number:

TQ312

YANG Xiaolong, LI Yongqing, YAN Xiaokun, CHEN Wenjing, MA Xiuqing. Research progress in gas barrier polymer/graphene composites[J]. China Plastics, 2021, 35(12): 145-153.

Figures/Tables 8

理论模型	适用条件	计算公式
Nielsen^［10］	平行且规则分布的纳米片层	$P P 0 = 1 - φ 1 + α φ 2$
Bharadwaj^［11］	片层与扩散方向呈角度排列	$P P 0 = 1 - φ 1 + α φ 3 S ″ + 12$
Nazarenko^［12］	片层团聚的影响	$P P 0 = 1 - φ 1 + α φ 3 n S ″ + 12$
Cussler^［13］	平行且规则分布的纳米片层	$P P 0 = 1 + α 2 φ 2 1 - φ - 1$
Lape?Cussler^［14］	平衡片层呈随机空间排布	$P P 0 = 1 - φ 1 + α φ 3 2$
Brydges^［15］	平衡片层呈随机空间排布	$P P 0 = 1 + α 2 φ 2 1 - φ γ (1 - γ) - 1$

理论模型	适用条件	计算公式
Nielsen^［10］	平行且规则分布的纳米片层	$P P 0 = 1 - φ 1 + α φ 2$
Bharadwaj^［11］	片层与扩散方向呈角度排列	$P P 0 = 1 - φ 1 + α φ 3 S ″ + 12$
Nazarenko^［12］	片层团聚的影响	$P P 0 = 1 - φ 1 + α φ 3 n S ″ + 12$
Cussler^［13］	平行且规则分布的纳米片层	$P P 0 = 1 + α 2 φ 2 1 - φ - 1$
Lape?Cussler^［14］	平衡片层呈随机空间排布	$P P 0 = 1 - φ 1 + α φ 3 2$
Brydges^［15］	平衡片层呈随机空间排布	$P P 0 = 1 + α 2 φ 2 1 - φ γ (1 - γ) - 1$

Tab. 1. Applicable conditions and calculation formulas of various theoretical models

Fig.1. Barrier model of polymer composites with different dispersed structures［16］

Fig.2. Hydrogen permeability coefficient of pure PET and its composite?coated PET films［23］

样品名称	温度/ ℃	氧气渗透系数/ cm³·mm·m^-2·atm^-1·d^-1	透氧性下降百分比/%
纯PLA	25	23	—
	35	33	—
	45	51	—
PLA/GR?0.1	25	18	22
	35	22	33
	45	31	40
PLA/GR?0.3	25	20	13
	35	23	30
	45	35	32
PLA/GR?0.5	25	22	4
	35	30	9
	45	40	14

Tab. 2. Effects of temperature and GR content on oxygen permeability of PLA/GR composite films

Fig.3. Gas permeability coefficient of PVA/GO composites［25］

Fig.4. Gas permeability coefficient of PLA/GO composite film［26］

Fig.5. Oxygen permeability coefficient of PET and its composites［27］

Fig.6. Oxygen permeability coefficient of （Fe3O4@GO）/PVA composite films

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